I have to take exception to something Nirav said in his post. As I said in my previous post, you can stagger the set pressures but you do NOT have to. Now, I don't really know what the European codes say but as far as ASME Section VIII, Div 1 goes:
"When the required capacity is provided in more than one
pressure relief device, only one pressure relief device
need be set at or below the maximum allowable working
pressure, and the additional pressure relief devices
MAYbe set to open at higher pressures but in no case at a
pressure higher than 105% of the maximum allowable
working pressure, except as provided in (

below."
Note the use of the word
May. If this was mandatory, then ASME would have used the word
SHALL. So you can have the set pressure of one of the PSVs at 105% of the MAWP (or design) but again, you do NOT have to.
I like his suggestion about seeing if the PSV vendor can change the "orifice" of the existing PSV but you will have to have the valve re-tested for certification. That is something the PSV vendor should do anyways if the valve is modified in any way. Note that a PSV really doesn't have an orifice in the true sense of an orifice, it has a nozzle.
Further to Nirav's statements. Yes, you must check the lines for the new capacity. I'm very concerned about both the inlet pressure drop exceeding the 3% rule significanly and increasing the built up backpressure against the PSVs. The former creating a chatter problem, which I mentioned in my previous post and the latter causing a loss of PSV capacity. NOTE, the 3% Rule is
NOT a code requirement. First, API is not code; it is a recommended practice, note the title API RP520/RP521. The "RP" stands for Recommended Practice. This is not code by any means. It can be considered "Good Engineering Practice", which is almost as good as code in my book but is not code (or law). Second, the 3% rule is actually stated in ASME Section VIII but it is included in the Nonmandatory Appendix M. Again, not code (law) but should be considered "Good Engineering Practice" nevertheless.
A final note to all or our readers and particpants. It's not that I want to be anal about the terminology and such. We must all recognize what is required by law(s) and what are standards, guides and just good engineering practices. We don't want to be doing things that will increase cost and really don't give us any safety benefit. Even the 3% Rule can be violated without consequence. I've written about this in articles published on this web site.
Thanks for your attention.