Please gat a copy of this extremely valuable book (free from Fisher).
http://www.documentation.emersonprocess.co.../book/cvh99.pdfYou will want to read Chapter 5. It will show you step-by-step how to work the equations for a control valve using the ISA standards, for either liquid or vapor/gas. What you want for your problem is to RATE (rather than sizie your control valve. You need the maximum Cv of your particular control valve and some other parameters defined in the handbook. You should have no trouble obtaining the data you need. You then assume the worse inlet pressure you can expect at the time of your scenario. The downstream pressure will the relief pressure. Using the maximum Cv and this pressure difference, you will calculate the flow rate using the equations from the handbook. This will be your relieving flow.
Cv is basically an indication of the capacity of the control valve.
Once you download this book, and read the material, post any specific questions you may have.