I'm a little confused because you do show what looks like a vent line from the boot going directly to flare via a locked-opened block valve and you show an equalization line going into the tank. If the vent line from the boot is indeed wide open to the flare then all the pad gas
should be by-passing the breather and emergency vent! However, from what you say the gas can't be doing this because the emergency relief is simmering?!? I have to conclude:
(1) The block valve is not opened as you indicate on the sketch but closed
or
(2) the vent line from the "boot" to flare is very, very small and is actually acting as a restriction
or
(3) some detail is missing on this sketch
To get more specific also means we need more information. For instance, what are the sizes of the lines from the boot? What type of breather are you using? You do know that these come in basically two flavors, one where there is a spring on the vacuum side and weights (pallets) on the pressure side or the other-way-around. Perhaps the spring is on the pressure side and is binding or broke and not allowing the pressure side to open. When these devices are delivered, they typically have a plate put in to protect the weights. This protection has to be removed before installation so that the weighs are allowed to move. If the weights are on the pressure side and this protection is still in place then that would not allow the brether to vent.
So, you need to check these things out.
If you are getting excessive pressure during filling then the breather is undersized; it isn't a matter of set pressure. The sizing basis for the pressure side of the breather is the maximum pump-in rate possible plus an associated thermal expansion rate. You must follow the procedure given in API 2000 or at least check API 2000 against what you currently have. By the way, you should have the calculations for this venting. If you don't, go back to the designer and ask for them!! If you can't go back to the designer, then you must generate them yourself now and use API 2000. On top of all this, you need to check the sizing of your vent system. Why? Because this whole design is suspect and at this point in time, you should be thinking the entire system is undersized. You need to prove it to yourself it is OK.
I also gave you a suggested setting for your pad gas regulator and suggested a pressure range for your pressure transmitter in my last post.
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What about the gas line connecting the tank to the boot. Do you think it is necessary for the relief system.
The boot must be protected as well as the tank but if the vent line from the boot is indeed wide open to the flare as shown in the sketch (but I question this) and it is of proper size to keep the "boot" at or below design pressure (during operation and for a fire) then it should not require an additional relief and you could then take out the equalization line to the tank. But if it needs protection say from a fire, then it can still be used to tie into the tank and allow the tank's emergency relief to handle the boot as well. This also means you need to consider the volume of liquid in the boot as an adder to the tank volume when determing the emergency relief requirements and you need to make sure the boot equalization line is large enough to handle the load from the boot to the tank during fire.
Art has experience in designing these systems whereas I do not so I'll let Art chime in with any specific design improvements he feels the system may need.
Again, check on the things I brought up and get back to us.