Please find the attached link,
http://people.clarkson.edu/~wilcox/Design/reliefv2.pdfThis gives a procedure to do the RV sizing for super critical condition. You will require hysys or other simulation software to do the property calculations. At relieving condition the fluid will be in dense phase & the orifice size calculated will be lower (may be D or E orifice).
We have came across similar situation many times, at normal condition the gas in KOD will be below critical condition but at relieving condition (ie. 21% over pressure {for ASME section 8 vessel} & corresponding relief temperautre ) the fluid will be above critical condition.
regards
Umesh.R