So essentially you want to find the time it takes to heat a vessel of water until it boils and the pressure reaches 6 bar? As to why it reaches a steady state at 6 bar is also a mystery. Im going to assume at that point in time, some valve is opened.
The time it takes to heat the water to the boiling point wrt the pressure inside should be pretty easy for you. Im going to assume you can do that. I believe your problem is in calculating when it boils, how long it takes to reach a certain pressure.
I shall start by assuming a closed vessel filled with a certain amount of water that is at atmospheric pressure and is at its boiling point.
Upon addition of a certain quantity of heat, some of it would boil. The vapor space above it would start to contain wet steam. Quality shall refer to the dryness fraction. The enthalpy of this wet steam would be as follows
Wet steam enthalpy = Enthalpy of evaporation * Quality + (1 - Quality) * Water enthalpy
Enthalpy values can be found from the tables for the starting pressure (atm press).
Solve for the Quality.
Specific volume can be found as follows.
Specific volume = Dry steam specific volume * Quality
With the specific volume, one can calculate the new pressure as follows.
Pressure = R * Temperature / Specific volume
Assuming the amount of heat added is small enough, this actual pressure would have little effect on the enthalpy values chosen and therefore no recalculation and iterations for the enthalpy and specific volumes are needed.
With this new pressure and the addition of another quantity of heat, repeat all the previous steps to obtain a new pressure.
Knowing the rate of heat addition, one would be able to keep doing the above for each time (and hence heat rate) step and would therefore have a temperature and pressure profile for a closed boiler with respect to time.
As you might have already observed, I have made some notable assumptions like the volume of water remaining the same throughout the time. It can be done much more rigorously by calculating the amount of water vaporized and the new specific volume resulting.
Edited by thorium90, 28 April 2013 - 01:09 PM.