Asalahi,
VMGSim has a dynamics engine able to model the system that you suggest. Furthermore, you will find the Blowdown Assistant to be a very useful tool for this particular case.
If your intention is to carry out a Minimum Design Metal Temperature (MDMT), VMGSim even offers the option to track the wall temperature separately for each phase in the vessel, as well as continuous updates of the HTC. VMGSim also keeps track of the kinetic head in all the unit operations, so you may be able to find lower temperatures in nozzles and probably after relief valves compared to other simulators.
If you want to evaluate a fire scenario, VMGSim has various standard fire models and also offers the user the option to input custom equations for this purpose.
However, before attempting anything in VMGSim, I strongly suggest to consider Art and Naser's comments regarding the proper specification of the system. Simulation software is a very valuable tool for the Engineer, but it should never replace a sound reasoning and understanding of the system. Results must be taken sceptically until proved otherwise.
Of course, if you need any help on using VMGSim, you can always contact the Technical Support team in your region.
Nicolau Goula