I am not sure whether you understand what TBP cutpoints are. They are not the same as boiling ranges.
In general: TBP cutpoints are determined by product drawoff rates.
It depends on the specific location of PA's and the type of product drawoff trays whether PA's will affect the amount of product that can be drawn off at various points in the column.
Assuming product drawoff trays are not total drawoff trays (which they should not be in a properly designed column), and as long as the pumparound duties in a column are not so high that there is not enough vapor passing through to sections above to be turned into products, PA's usually have no impact on possible product drawoff rates. They do however have a big impact on the fractionation between products as they affect the V/L ratios in the column sections. This impact will be visible in the product boiling ranges and in the 95% - 5 % ASTM gaps and overlaps between adjacent fractions. As such they also have impact on other product properties such as smoke point, cetane index, density, viscosity and pour point. To avoid that these properties do not meet specifications it may be necessary for the operator to adjust product drawoff rates, when PA's are changed.
Edited by PingPong, 25 August 2014 - 01:17 PM.