Just to add to whats all said before,
Rated or nameplate capacity of any relief valve is stamped on the valve and matches the flow of compressible fluid (say steam) at saturated conditions of discharge. To obtain the relieving capacity at particular relieving point of set pressure and temperature, use the correction factors given in API-520 or ASME Section-I for superheat temperature, pressure > 1500 psi, type of PSV arrangement.
My experience tells that, for everything else remaining constant, the relieving capacity in superheated conditions is less than rated or nameplate capacity (which of course corresponds to saturated condition)