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Urgent Chemical Engineering Problem. Please Help.


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#1 geo123

geo123

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Posted 15 April 2015 - 04:02 PM

I just want to ask question about this as I'm not sure what I to do next:

The product gas from a combustion reaction has the following dry basis molar composition:
CO2 80.35%
CO 4.73%
SO2 0.03%
O2 14.89% 
Pure oxygen is fed to the furnace in 10% excess of that required for complete combustion. There is no oxygen in the fuel (fixed or gaseous). Calculate the elemental composition of the fuel (mole % of elements C,H & S). Base calculations on 100 moles of dry outlet gas.
 
Take SO2 to be the fully combusted form of S. 
Here is my working so far:
'O'in='O'out
2*'O2'in=2*'CO2'out+1*'CO'out+2*'SO2'out+2*'O2'out+1*'H2O'out
 
2*'O2'in=2*80.35+1*4.73+2*0.03+2*14.89+1*'H2O'out
 
'C'in='C'out
'C'in='CO2'out+'CO'out=80.35+4.73=85.08mols
 
'S'in='S'out
'S'in=1*'SO2'out=1*0.03=0.03mols
 
0.1=(O2feed-O2theoretical)/(O2theoretical)
 
Complete combustion
S+O2->SO2              0.03mols O2
C+O2->CO2             85.08mols O2
H2+1/2O2->H2O     x mols       O2
 
Incomplete Combustion
C+1/2O2->CO
 
The answer is 
  1. C 34.63%

    H 65.36%

  2. S 0.0122% 

  3. But the problem is that I do not know how to get to this answer. Please explain it to me step by step and/or the solution(maths/algebra behind it)

Thanks.


Edited by geo123, 15 April 2015 - 04:23 PM.


#2 Bobby Strain

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Posted 15 April 2015 - 04:19 PM

Even though I loathe spreadsheets, your work would be better presented with one.

 

Bobby



#3 breizh

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Posted 15 April 2015 - 10:18 PM

Hi ,

Let you work with the numbers and the equations .

Good luck

Breizh

#4 Napo

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Posted 16 April 2015 - 07:31 AM

Dear Geo123,

 

The solution of Breizh is excellent!!.

 

Maybe if you want a manual form, I send you the information.

 

Regards,

 

Napo.

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