yes, the standard hydrate model in Prode Properties is limited to 220-310 K temperature range as reported in operating manual,
if you wish to go outside that range ask for the complex model (slower but more accurate at low temperatures),
anyway I think you can manage the problem in most cases even with standard model,
if you wish to model the valve setting Hout = Hin the HP-VLSH flash works for tout in the range 220-310 K
while the HP-VLS flash of course works outside that range,
for example, if you set as model for solids SPM-CPA you may solve a HP-VLS flash and then evaluate formation of hydrates at final temperature...