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K-Values For Aromatics


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#1 ChemEngStudent17

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Posted 18 July 2017 - 09:39 AM

Hi all,

 

I'd like any suggestions on literature where I can find equilibrium k-values (used in industry) for aromatics components,

 

Thanks!



#2 Pilesar

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Posted 18 July 2017 - 11:04 AM

Consider using the Student Forum at this site for student-related questions.

A component's K-value (the ratio of the mole fraction of a component in the vapor phase to the mole fraction of a component in the liquid phase) depends on system pressure and temperature so is usually predicted by a thermodynamic method previously found to give good results for similar applications. At low pressures, mixtures of aromatic components can be treated as ideal so you can calculate K from the partial pressures of the components. At higher system pressures, you will get more accurate results using an equation of state like PR or SRK. 



#3 breizh

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Posted 18 July 2017 - 09:34 PM

Hi ,

you may consider this resource to support your work .

http://www.questcons...oftware/canary/

 

Hope this is going to help you.

 

Breizh



#4 ankur2061

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Posted 18 July 2017 - 10:44 PM

Hi,

 

Refer the link below. The spreadsheet attached in the link has DePriester charts depicting K-values for hydrocarbons. Also extensive VLE K-values are provided in "API Technical databook":

 

https://www.cheresou...hase-separator/

 

Also refer another link for empirical method of calculating K-values for a given range of pressure:

 

http://www.jmcampbel...rmine-k-values/

 

Regards,

Ankur


Edited by ankur2061, 18 July 2017 - 10:48 PM.


#5 ChemEngStudent17

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Posted 24 July 2017 - 11:02 AM

Hi,

 

Much appreciated to you all! Your info was very helpful!






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