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More on Biopolymers

     The field of biopolymers, while still in its early stages, is growing in popularity everyday.  Some biopolymers can directly replace synthetic plastics in traditional applications, while others possess unique properties that may open new applications.  For most biopolymers, it's still too early to determine if they'll be economically feasible on a large, industrial scale.
     When you run into a spider's web, the last thing on your mind is, "What a great a material!"  But consider that the spider's silk has a tensile strength 16 times greater than nylon!  At the same time, silk maintains a very high degree of elasticity.  Attempts to manufacture gentically modified silk have thusfar been disappointing due to low yields.  If this can be improved, silk can be applied to many applications.
     Chitin, a polysaccharide found in the exoskeletons of insects and shellfish, possesses many desirable characteristics.  Chitin's most important derivative, chitosan, is nearly a "model" biopolymer with it's useful physical and chemical properties, high strength, biodegradability, and nontoxicity.  In fact, chitosan brings new meaning to the word "biodegradable" as the human body easily breaks it down into simple carbohydrates, carbon dioxide, and water.  This accounts for the research that is trying to use chitosan in drug delivery systems.
     Lactic acid is produced by the microbial fermentation of sugars such as glucose or hexose.  Feedstocks can include potato skins and corn.  The lactic acid monomers can be used to create low or high molecular weight polylactide polymers.  PLA commodity polymers are being developed for use as pulping additives in paper manufacturing and as biodegradable packing materials.  PLA's current price level of $5.00/lb (US) will have to be significantly improved upon before it gains wide acceptance.  Currently, the medical community is the primary user of PLA.   Absorbable sutures such as Vicryl™ are made of 90% PLA and 10% polygylcolic acid (PGA).

Table 1:  Current US Suppliers of Biopolymers

Company Product Application Comments
Zeneca BioProducts BIOPOL resin Films and coatings Assessing full production
EcoChem (DuPont) PLA-PGA copolymers Medical and packaging 100 million lb/year facility opened in 1995
Cargill, Inc. Polylactide Packaging 10 million lb/year facility open
Argonne National Labs PLA from potato waste Packaging Available for license
Warner-Lambert NOVON structural material 100 million lb/year facility opened in 1992


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