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Need Help With Entering Kinetics Into Hysys


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#1 Hysysfysys

Hysysfysys

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Posted 23 February 2015 - 02:18 PM

Dear all, I am currently stuck trying to insert a reaction kinetics into HYSYS. I am using a heterogenous catalytic reaction in HYSYS, and my reaction is as follows:

 

r= kKMeOH(PMeOH −((PDMEPWater)/(PMeOHKeq))) / (1+KMeOHPMeOH +KWaterPWater)
 
where 
k = 3812.11 exp (-69383.66/RT)
 
K= 67.42 exp(108108.6/RT)
 
Kw = 2.17 exp( 89828.61/RT)
 
As you can see, I have the kinetic parameters available and HYSYS requires the input of A and E of the forward and backward reaction. Currently, I am thinking that the A and E of the forward reaction would be the product of of k and Kmeoh. However for the reverse reactions I believe it would be kKmeoh/Keq  and I do not have the values for Keq so I am wondering how should I put this into HYSYS. 
 
As for the terms that took the adsorption of reactants/products onto catalyst, I have inserted them into HYSYS but any help or knowledge regarding that is appreciated as well. 
 
Regards,
Fysys


#2 thorium90

thorium90

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Posted 13 March 2015 - 01:11 PM

It sounds like you have langmuir hinshelwood kinetics and you are mistakenly trying to input it as reversible kinetic reactions.


Edited by thorium90, 13 March 2015 - 01:11 PM.





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