Ive drawn a very rough diagram below as to how i understand it, a. is a total condenser b. full reflux condenser

I also assume the vapour distillate and the reflux compositions are going to be the same, or am i wrong? Thanks!
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Posted 22 March 2010 - 10:55 AM
Posted 22 March 2010 - 11:29 AM
Edited by Zauberberg, 22 March 2010 - 11:32 AM.
Posted 22 March 2010 - 11:03 PM
You are right about the concept of total reflux. All liquid from the overhead receiver is refluxed back to the tower - there is only vapor product from the reflux drum. A common example of total-reflux system is Sour Water Stripper (SWS). That corresponds to the sketch "b" in your attachment.
Answer on your second question is: NO, because vapor and liquid composition will depend on the overhead stream composition and vapor-liquid equilibrium (ideally: Raoult and Dalton law) at overhead receiver conditions (p, T). Again, you can refer to the SWS example where liquid phase is mainly water (saturated with acid gas at vessel conditions), while vapor stream is acid gas saturated with water at the same conditions. In reality, these two compositions will never be identical unless you are condensing 100% pure component as overhead stream.
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