tafolabi,
I know this type of plant, I have designed several such plants. You have a difficult assignment.
First I would say that it is surprisingly difficult to take an accurate mass balance from an operating plant. To do this you first need to find where all the various vent and drain streams and other offtakes are and ensure that they are closed or else have a means of measuring them. This includes the acid gas from the amine unit, the fuel gas, the waste water etc. Then you need to get good calibration for the flowmeters and learn how these instruments are corrected for temerature, pressure and density to get a reading in mass flow units (not volume flow). Then you need to get a good composition analysis of the feed and product streams.
Calibrating the temp and pressure instruments is important, if possible. You can easily find two temperature instruments on the same stream with different readings - which one do you believe?
Level instrument output is always given as Percent which is useless until you have the Range, and the zero setting. If you want to know the flow of a stream from a vessel,such as a compressor KO drum, which has no flow measurement, you can do it by closing the valve and timing the rise in level between two points, if the operators will let you do this. You could cause a high level trip which will shut down the plant.
Make sure you can get printed historic trends from the control system of as many variables as you can manage. Then if there is an unexpected spike somewhere you could try to correlate it with readings of other variables at the same time.
Measure the flows of utility streams to the reboilers and the supply and return temperatures, so you can do a heat balance on the columns. Doing a heat balance on an aircooler is going to be difficult.
Good luck
Paul