do you mean to calculate vapor composition including water and other components in vapor phase at specified operating conditions ?
with a different software (Prode Properties) I simply add a vapor liquid separator and get the saturated vapor stream,
you can do the same with Aspen or use the specific operation (many threads discussing this),
take care to select the correct thermodynamic model as several components as water and methanol can show non-ideal behavior
(with Prode I select a EOS with complex mixing rules, for example Peng Robinson - NRTL with Huron Vidal or Michelsen rules)
if, instead, you wish to design the tower , there are old posts by Art with Excel files which may help.