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Nitrogen Blanketing For Chemical Tanks


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#1 mykid

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Posted 26 April 2011 - 10:41 PM

Hi I have some questions in regards to the design of chemical tanks.

Our client has bought few chemical storage tanks with the following details:
working pressure - 4 bar internal, 0.42 bar external
Test pressure - 6 bar
Capacity - 4200 liters.

This is for storage of PPD and Corrosion inhibitor.
PPD has a flash point of 29°C and Corrosion inhibitor has a flash point of 50°C.
By definition, these two chemicals are classified as flammable liquid. Therefore nitrogen blanketing is recommended.

However i found a code in API 2000 section 4.4.1.4 which states that open vent with no flame arrestor is acceptable for tank less than 9.46m3 for any product.

Has anyone use the above to justify their design without nitrogen blanketing?

1. What is the design pressure of these tanks? The PVSV provided by the tank supplier is set at 4.4bara and vacuum 0.21bara. Working pressure refers to operating or design pressure of the tank?
2.If nitrogen blanketing is provided, do we stiill require vacuum relief in case of N2 valve failure during pump out? if yes, is it allowed to have air entering the tank given that the gas is flammable? The PSV will be retained for emergency relief.
3. Is it allowed to have a common N2 back pressure regulator together with a PSV sized for CV failure on the common header and connected to few different tanks? I understood that for normal operation where set point is close to atm, it will be difficult to detect the low pressure in any of the tank. However if the set pressure of N2 is 3 barg, this should not be a problem. (Not sure why they set teh N2 at 3 barg at teh first place)

Anyfeedback is welcomed and thanks.

#2 Art Montemayor

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Posted 27 April 2011 - 11:38 AM



Mykid:

By using the acronym PPD, do you mean “Paraphenylene-Diamine”. If so, please always state it before using the acronym.

You have a 1,100 gallon-capacity tank with a design pressure of 60 psig. You should forget all about API 2000. You are wasting time on a document that does not apply to what you have.

If your “PPD” is flammable, then you had better stick to applying an efficient nitrogen blanket on it. Forget about an open vent. If you don’t believe or trust me, check with your Singapore Fire Marshall. I am sure they will tell you the same thing.

Your design pressure should be stamped on your tank’s code name plate. It should be at least the test pressure divided by1.5. In your application I would not set the vacuum any lower than approximately 10” of water column – but check that with your vacuum design pressure. If you are applying a vacuum breaker, then YES, you have to allow air to enter to break the vacuum. That is the design of a vacuum breaker.

I can’t comment to your question #3 without you furnishing a detailed P&ID, showing all the piping and instrumentation.

For this type of nitrogen blanketing application I always incorporate a radar type of level detector that keeps a continuous readout on inventory and activates both high and low alarms on the tank. I also install a backup level detector (of another type) as a safeguard. I monitor and install a pressure transmission on the nitrogen blanket pressure and also install a mechanical limit switch on the vacuum breaker to alarm and give notice when the vacuum breaker has opened. This immediately alerts all to the migration of atmospheric air into the tank. This event should be recorded.

Needless to say, all tank incoming liquid should be introduced into the tank without generating any static electricity – i.e., the liquid should not be allowed to “free-fall” into the tank, causing splashing and agitation. Normally, a dip pipe is used with an anti-syphon vent hole for this purpose.

I hope this experience will help you.


#3 fallah

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Posted 27 April 2011 - 12:39 PM

mykid,

The blanketing system for your storage drum,let say pressure vessel,included following items,

-A PCV for supplying nitrogen during drum unloading and maintaining the operating pressure of the drum.

-A PCV for releiving the pressure would be created during drum loading which its outlet usually may be connected to flare header.

Indeed,a PSV with set pressure equal to drum design pressure would be installed on the drum to prevent any overpressure caused by blanketing system failure or other applicable scenarios.

Fallah

#4 mykid

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Posted 27 April 2011 - 07:37 PM

Art,

Thanks for the reply. PPD: Pour point depressant.

I was wondering initially if API2000 applies in this application since it is operating at atmospheric. However, the client has bought a pressure vessel instead.

I am waiting for the vendor to confirm on the design pressure of the tank/vessel.

#5 proinwv

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Posted 28 April 2011 - 01:50 PM

Am I missing something here?

Is the tank operating at several bars pressure? If so how would you consider an open vent?

Is it operating at atmospheric? If so how would you blanket it?

Regardless, I do not believe that API 2000 tells you when to blanket. That is not what the primary purpose of it is. If you have a flammable then you should consider blanketing it for safety with the appropriate P/V and emergency vents as well as the other safety controls mentioned previously.

#6 mykid

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Posted 03 June 2011 - 12:36 AM

Hi Prov,
The tank is blanketted at 3 barg with Nitrogen. Vessel is designed for 4 barg/42bara vacuum.
The PVSV setting is at 4.4 barg/21 bara vacuum.

This is a portable tank.

We have added a PCV set at 3.5 barg on the vent line for outbreathing due to thermal expansion.
Currently this will be used to store Methanol, and the tank will be changed out when it is depleted.

I understand that this tank (or should be called vessel) does not fall under API 2000, however the latest API 2000 has a section on inert gas blanketing that states the requirement of flame arrestor.

My question is the following:
1. if the vessel is blanketted with nitrogen, why is flame arrestor still required? the vapor present in teh tank will be mainly inert gas. In addition flame arrestor requires regular maintenance and easily blocked. It may cause overpressure of the tank if the flame arrestor is blocked.

2. It also states the requirement of low low pressure to trip the liquid outlet. Is this really required? I have not seen many plant with this kind of design. We can have a pressure transmitter with low and high alarm, but is it required to trip the system? The tank is anyway protected with PVSV.

3. Since the tank is portable, it comes with a PVSV that vents locally. Is this acceptable? i.e. to overcome vacuum, it will suck in air instead of N2, if it is overpressure it will be vented locally instead to safe location.

#7 Mechanika

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Posted 15 July 2011 - 09:52 AM

Local venting of a portable unit is dangerous as methanol is toxic. You can vent to atmosphere, but you've got to have extra precautions in place like breather masks or an established hazard zone around the vessel.

Additionally mixing air with methanol in a confined space is dangerous as it drastically increases your chance of an explosion. By letting more air into the tank, you are giving the chemical more of an opportunity to vapourize as your blanketing medium is not an inert gas.

These documents should shed some additional light on your questions.

Attached Files



#8 parto

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Posted 17 October 2011 - 01:25 AM

is it right that the Tank Blanketing Valve's set pressure is 25% of tank design pressure and Breather vent is 50% design pressure tank? is just a guide line or a rule? if this is a rule, what is the basis?

#9 fallah

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Posted 17 October 2011 - 03:51 AM

is it right that the Tank Blanketing Valve's set pressure is 25% of tank design pressure and Breather vent is 50% design pressure tank? is just a guide line or a rule? if this is a rule, what is the basis?


parto,

There is no specific rule for setting of safety divices on the storage tanks, other than you should try to set them such that they would operate and protect the tank between MAWP and MAWV and by considering adequate dead band their operation haven't any interference with each other.

Fallah

#10 proinwv

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Posted 17 October 2011 - 07:09 AM

Fallah is correct. You must look at the operating band of each component to insure that there will not be interaction between devices and that the tank limits are not exceeded, or for that matter, not approached.

To do this you will need to obtain operating characteristic information from each manufacturer that describes the complete pressure response of the device. For example, for a pressure vent you need:

Cracking pressure
Pressure to open to the desired flow rate
Pressure to fully open
Pressure to reseat the vent on pressure decline.

Paul

#11 proinwv

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Posted 17 October 2011 - 07:11 AM

The third item should read:

Pressure to open fully and the flow at that pressure.

#12 parto

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Posted 23 October 2011 - 10:17 PM

Dear Fallah and Mr.Proinwv, thank you for your advise.it's realy precious experience which i can learn.

#13 Danybony

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Posted 24 May 2012 - 10:35 AM

Hello everybody! I have a similar situation to deal with: a 2 m^3 tank filled with a Pour Point Depressant with a flash point of 59 °C. The tank is closed and a flame arrestor is provided on the vent line. I have done some calculation and it seems that the temperaure of 59 °C cannot be reached even in summer unless the tank is left at the minimum level for two/three days. Do I need to blanket it with nitrogen or not? If yes, which is the API i should refer to? Thank you.

Daniele

#14 fallah

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Posted 26 May 2012 - 02:59 AM

Danybony,

How much is the VP of the fluid?

Anyway with such low volume of the tank it don't seem to need blanketing system.

Fallah

#15 Danybony

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Posted 28 May 2012 - 01:25 AM

Hello Fallah, thanks for the answer! I don't know the exact VP of the fluide since it's a mixture of three components with varying composition: Heavy Aromatic Naphta, Naphtalene, 1-2-4 trimetilbenzene. I've got an additional question: how would you handle the eventual overflow occurred in tank loading by a truck or handloading? Would you let it out on the drip pan or not?

Daniele

#16 fallah

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Posted 28 May 2012 - 03:02 AM

how would you handle the eventual overflow occurred in tank loading by a truck or handloading? Would you let it out on the drip pan or not?


Daniele,

For a tank with nitrogen blanketing, an overflow with a seal leg, that would be terminated to atmosphere or closed drain, is commonly used.

Fallah




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