15 replies to this topic

[rohollah]

Dear experts

As you can see in attached P&ID,there is a methanol storage tank with N2 blanketing system.

Tank design pressure=150mmH2O

Psv set pressure=120mmH2O

PCV set pressure=100mmH2o

Max ambient temperature=60°c

Our engineering department are going to change PCV set pressure to 50mmH2o.

Is it ok to decrease PCV set pressure regarding to mentioned conditions?

What parameters should be considered in order to determine the correct set pressure for PCV ?

Is there any relevant  reference or standard?

Regards

Rohollah 

Attached Files

•  U814 Model (1).pdf   41.42KB   110 downloads

[fallah]

Rohollah,

 

At first, you should know changing the PCV set pressure cannot be possible in a wide range and according to vendor justification might be done within +/-5%. Indeed, changing the set pressure of PCV should be done considering set pressures of other safety devices (depad valve, emergency vent,...) already installed on the tank in dead band and safety margin standpoints.

 

Methanol is a liquid with high vapor pressure (around 3 psia @25 C and 12 psia @60 C).Then in the normal temperature range, let say between 25-60 C, neither with PCV set pressure of 100 mmH2O nor with 50mmH2O, mentioned PCV will not be opened and just the PSV (as a vent) will be opened due to higher vapor pressure than the PSV set pressure.

 

Then considering above characteristic, Methanol is normally stored in a pressure vessel (rather than in atmospheric tank), let say with design pressure of 3-4 barg, along with the N2 gas blanketing to avoid continuous waste of the Methanol vapor through the vent.

[proinwv]

In addition to what Fallah has said, let me add that when looking at these devices be aware that each has it's own operating pressure band which must be considered when the various setpoints are determined so that there is not any interaction between devices.

 

Please do a search on this forum and you will find many useful comments made in the past by the experts.

[Art Montemayor]

Rohollah:

 

The Hottest Place on Earth ever recorded was El Azizia in Libya where the temperature reached a scorching 136 ^oF (57.8 Celsius) on Sept. 13, 1922.

 

Do you live in El Azizia?   Even if you did, the local temperature has not reached that level again since 1932 and I don't think 60 ^oC is realistic - or wise - as a design temperature (unless you are designing for a surrounding pool fire.

 

Where is the methanol tank going to be located?  Tell us so we can have a clear idea of what maximum temperatures are credible.  60 ^oC is not a credible ambient temperature.   This is important to identify because, as Fallah has pointed out, it impacts on the mechanical design of the storage tank.

[proinwv]

Good call Art. I somehow missed that!

[gegio1960]

I have a question on this point.

I suppose the max temp mentioned by Art isn't taking into account the sun radiation effect.

How this effect is considered in the tank design?

I'm asking this since, in some projects, the clients asked to consider the so-called "black body temperature", up to 70-80°C in some middle-east locations against max ambient temp of about 50°C.

I can imagine this effect will be reduced by light painting and isolation but I'd like to have an expert advice.

Thank you,

gegio

[fallah]

gegio,

 

Yes, in some middle east areas maximum ambient temperature could be even above 50 C (in a plant it is 52 C) and in those locations design temperature of the storage tanks for mechanical design are to be considered as high as 85 C due to solar radiation. The design temperature could be reduced by applying the light painting or insulation but customarily credit wouldn't be taken for such applications to reduce the design temperature.

Edited by fallah, 11 September 2013 - 12:50 AM.

[rohollah]

Dear Fallah

with all due respect to you,

Is there any reference for mentioned tolorance(±5%set pressure)?

Regards

Rohollah

[fallah]

Dear Rohollah,

 

Set pressure range of the PCVs are to be specified by relevant vendor(s). But as far as i know, pilot operated PCVs could be set at wider pressure range...

[rohollah]

Art

In addition to what Fallah has mentioned ,I Should say that ,believe me or not I myself have measured 60 c at the tank roof.

Anyway accordind to mentioned conditions and ambient temperature 50 c which set pressure should be selected for PCV?

Regards

Rohollah

[rohollah]

Fallah

 

Regardless of correct set pressure, if we set PCV at 50 mmH20 then in normal operation tank pressure will be 14.8 psia.  so in this case, tank pressure is higher than methanol vapor pressure @ 60 ^oC (12psia) then no vapor is produced and PCV should be open .

[latexman]

I see no problem with 50 mm H2O (2" w.c.).  I recall seeing PCVs advertised that work down to 6 mm H2O (0.25" w.c.)  Some even say they work in a slight vacuum!

 

See http://en.wikipedia....Tank_blanketing .  "Although it varies from application to application, blanketing systems usually operate at a slightly higher than atmospheric pressure (a few inches of water column above atmospheric). Higher pressures than this are generally not used as they often yield only marginal increases in results while wasting large amounts of expensive blanketing gas."

 

Another reference I use - http://www2.emersonp...orRecovery.aspx

 

Consult the existing PCV vendor for modifications recommended for good control at 50 mm H2O.  If good control is not possible with existing PCV, research other vendors PCVs using more advanced technology and obtain quotations.

[fallah]

 

Rohollah,

 

Please be informed vapor pressure is a partial pressure; means 12 psia is partial pressure of the methanol in tank's vapor space at 60 C. Then as far as the pressure in tank's "vapor space" is at or above 50 mmH2Og (or absolute pressure of 14.7 psi+50 mmH2O) as PCV set pressure, the PCV won't open to release the N2 into the vapor space.

Edited by fallah, 11 September 2013 - 11:07 AM.

[rohollah]

Fallah

 

As a result I have come up to this idea that,while the pressure in tank's vapor space is less than vapor pressure, PCV won't open to release the N2 into the vapor space.

 

In 100mmH2o the pressure in mentioned space is steel less than methanol vapor pressure @ 60C.

[latexman]

Rohollah,

 

"Regardless to correct set pressure,if we set PCV at 50mmH20 then in normal operation tank pressure will be 14.8psia.so in this case thank pressure is higher than methanol vapor pressure@60c(12psia) then no vapor is produced and PCV should be open."

 

If I may, it's not that black and white.  The liquid methanol is below it's boiling point at 60 C.  It still has vapor pressure that is contributing as a partial pressure to the total pressure of the tank.  The PCV may be controlling around it's set pressure.  At any instant, it may be open and it may be closed.  It will work to maintain 50 mm H2O g.  It is a dynamic situation.  However, if the tank has recently been filled, the tank may be at about 120 mm H2O g due to the PSV breathing out. Then, the PCV will be closed.  It should not open again until the tank level descreases and the vapor space decompresses, or the head space leaks down to the PCV set pressure (yes, some tanks/equipment are not perfect).

 

[fallah]

 

 

Rohollah,

 

The PCV will open as per the total pressure in vapor space rather than only methanol (or any other fluids) vapor pressure. If it set to be opened at 50 mmH2Og it will open at that set pressure to compensate any pressure reduction due to tank emptying, vapor condensation,..., regardless of the stored fluid vapor pressure. The special point about the methanol is: because it has high vapor pressure, the waste of methanol vapor would be so much through venting when to be stored in atmospheric tank even with N2 blanketing... Then it is better to be stored at higher pressure in a pressure vessel...