by definition cricondentherm is the maximum temperature on VLE area,
usually one calculates the phase envelope to find cricondetherm,
for some examples of phase envelopes see
http://www.prode.com...aseenvelope.htm
for a natural gas mixture, a EOS such as Peng Robinson or Soave Redlich Kwong
can predict VLE lines with errors of 1-3 K
which may be higher for very non ideal mixtures,
as far as I know there are not standards for this topic,
you may correct values for maximum (expected) error,
also don't forget that cricondentherm gives a conservative value,
if you know that a plant operates below a certain pressure
(which is below cricondetherm pressure)
you can, for example, calculate the dew point line up to that
value and select the maximum dew point.
Finally, cricondentherm is related to composition,
if for some reason, you add heavy components
cricondentherm must be recalculated.
Edited by serra, 07 July 2014 - 04:54 AM.