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Mathematical Criteria For Distillation Column Flooding


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#1 Guest_Shen_*

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Posted 07 January 2009 - 01:14 PM

Hi there, I'm a student working at U of T and I was recently assigned to a project to reduce the energy requirement of a general biodiesel plant with ASPEN simulation as my guide.

In designing my base case and attempting to optimize the distillation columns (I have to distill nearly all the methanol out of a methyl oleate, methanol, glycerol, oleic acid, NaOH mixture) I realized that certain settings such as changing the distillate rate and reflux ratio/# of stages caused an error to occur saying the rectifying section of my column had zero vapour or liquid flowrate. This means that the column is flooding (or the opposite).

I was wondering, what are the design parameters that cause flooding? What are the limits of these design parameters? I read somewhere that column flooding is caused by too great a vapour velocity in the column, and that this velocity is dependent on column diameter. But.... I didn't set any column diameter in ASPEN and it still floods (or the opposite). The column seems very sensitive, any change in distillate rate, reflux, reboiler duty, etc. may cause flooding (or the opposite).

For these reasons, I really need to find out how flooding is caused and what causes it, and what are the limits relative to reflux, # of stages, distillate rate etc. that cause flooding?

Is there at least some reference site I can find this information on?

Thanks in advance.


#2 astro

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Posted 07 January 2009 - 08:30 PM

I think you need to separate your thinking about this problem.

First you need to achieve feasible separation in terms of mass transfer, then, second account for equipment specifics associated with entrainment/flooding/weeping/choking (if you need to get that far).

Go back to basics and have a look in your standard student textbook - Perry. Ed 7 devotes chapter 14 to Gas Absorption and Gas-Liquid Systems. Look at diagram 14-2 where it depicts the feasible operating regime of a generic system G/L contactor. If your simulation places your operating point outside the feasible region, the computer won't lie and will tell you just that but use an error message such as "zero liquid flow", or similar. Your situation may well be that the feasible region is very narrow / small and therefore very sensitive to change.

There are following sections devoted to determining the number of theoretical trays or packing transfer units / height required.

Once you've got the theoretical separation that you're after, then start to look at detail issues such as the type of column internals and the specific choices that are associated. Then your problem becomes one of hydraulics and separation efficiency. Go ahead now to figure 14-23 (trays) & 14-46 (packing) and you'll see the impact of the hydraulic balance that is separate from the VLE issues considered previously.

You're tackling a mixed bag of components. When faced with difficulties like this, a good option is to use data from a model that solves or use actual plant data and achieve convergence first. Simulations will tend to solve quicker and more reliably the closer you are to the solution, which unfortunately is of little help if you're starting from scratch with a clean sheet of paper and limited references to consult.




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