12 replies to this topic

[rahulchem2005]

Dear all,

 

In existing tankfarm area we have nitrogen blanketing designed for push-pull method ( only for pump in/out and not for thermal inbreathing/outbreathing).

 

The tanks are protected for thermal inbreathing and outbreathing with PVRV (Pressure Vacuum Relief Valves).

 

How to ensure that during PVRV operation the air ingress (oxygen ingress) shall be below the LEL (lower explosivity level) of the fluid in tank?

 

Would like to hear for your guidance.

[fallah]

Hi,

 

You could size the nitrogen blanketing valve (pad valve) based on pump out+thermal inbreathing flow rate; then the air ingress might be happened just in vacuum vent activation to be opened due to an abnormal conditions.

 

To ensure the air ingress to be below the LEL you can use an oxygen analyzer activate an alarm on the high oxygen concentration... 

[rahulchem2005]

As the existing nitrogen storage is limiting, we cannot size the nitrogen blanketing valve for pump out+thermal inbreathing flow rate.

 

However I understand that a oxygen analyzer inside the tank will detect high oxygen. Is it a practical solution and is it generally followed in industry to install analyser inside tank.

 

(Are there any calculation by which I can prove that the LEL will not reach incase of PVRV opening and allowing air ingress. i.e considering some vapor space in tank and oxygen thru air ingress for thermal inbreathing case only)

[proinwv]

I agree with fallah and would add (to your reply) that it would be best to work toward increasing the supply of N2.

 

While an oxygen sensor may well tell you the level of O2, there may well be different concentrations throughout the vapor space at any particular time. Also, if you reach the LEL then what is your plan?

[rahulchem2005]

Yes..I agree with you Sir. O2 analyser may not be so fruitful.

 

Are there any method/reference to find out the LEL in the tank for the fluid. 

[proinwv]

If you need to find the LEL for a particular fluid, I would think that if it is a known fluid, it should be published. If not then I would think that it would require a laboratory evaluation. However, understand that I am a mechanical engineer, and hopefully one of our chemical engineers will be able to give you a better answer.

 

Again, I caution you that if the tank is breathing atmospheric air, with a flammable fluid in the tank you are in a dangerous area. At some instant at some location, you likely will have the fuel, and the oxygen and just waiting for an ignition source. A spark, static electricity from pump-in or the like.

 

This brings to mind that you need to be doing whatever possible to reduce the possibility of static build-up which among other factors can be present due to pumping velocity, friction from inline filters etc. I would look into sources like the API for information on this.

 

And lastly, should the unfortunate happen, a fire or explosion, it will be damn hard to justify not protecting against this event. It will not even look like and "accident" to some people.

[rahulchem2005]

True Sir...As a process engineer ..its my duty to have optimum design of plants with safety...!!!

[proinwv]

Then I have nothing to add, and wish you the best of luck.

[Art Montemayor]

rahulchem2005:

 

You are a new member and I would add to this thread the fact that you have had the privilege of receiving some very sage and experienced advice as well as recommendations from two of our most experienced and respected members.  If you are indeed confronted with a potential hazard being created by the intake of atmospheric air into a storage tank filled with a very combustible liquid, then the best advice is as ProinWV has indicated: Simply do not allow the scenario of generating a partial vacuum condition in your tank while pumping out and causing the PVSV to open and allow atmospheric air to ingress and mitigate a potential vacuum condition.  I have been confronted with a similar situation in several applications in the past and the best practice was always ruled to ensure that sufficient nitrogen (or inert gas) was present and available to inject into the tank’s vapor space and avoid a partial vacuum.  That, positively, is the best and safest measure you can take.

 

In previous calculations that I generated I found that in my applications, I only had to size the capacity of the nitrogen feed valve to satisfy the pump-out condition (without adding the capacity required for inbreathing).  I found that the pump-out RATE was much higher than the inbreathing rate and safely sized it for the pump-out.

 

If you simply haven’t been given enough nitrogen volume (not flow rate) to satisfy the amount needed to mitigate the pump-out condition, then you can substitute another inert gas - carbon dioxide - through the use of high pressure cylinders.  However, you will have to superheat the CO₂ since the cylinders are filled with liquid CO₂ and the expansion will cause a temperature drop.  I used a copper coil immersed in the basin of my cooling water tower to supply the required superheat to the regulated CO₂ gas and this worked very well in one application.

 

Fallah’s comments on the use of an oxygen analyzer to alarm at the set LEL position are very valid.  This will tell you if have approached a hazardous situation - assuming that you have a sufficient dead band in your tank’s measurements.  But as proinWV has pointed out ….. then what do you do?  You still need an inert gas to mitigate what is a potential explosive situation.  You still have the responsibility of purging out the undesired oxygen and you need more inert gas for that - very quickly - in order to re-establish a safe condition..

 

If you are indeed aware of what level of hazard may exist and are very concerned about it, then I strongly advise you to follow our member’s comments and demand that your tank have sufficient inert gas supply available to it at ALL times while it is in operation.  Additionally I would add that all parts of your storage system should be 100% grounded - during storage operation, loading, and unloading.  The grounding connections should be checked visually and reported at least once a day - or every shift.  Should an incident occur - God forbid - then all these points will be questioned and documentation will be demanded by local safety authorities.

[proinwv]

Rahulchem 2005

 

Art has summarized this very well for you. I suggest that you have received information with $1million or more. Use it wisely.

 

Paul

[fallah]

[quote]

In previous calculations that I generated I found that in my applications, I only had to size the capacity of the nitrogen feed valve to satisfy the pump-out condition (without adding the capacity required for inbreathing). I found that the pump-out Rate was much higher than the inbreathing rate and safely sized it for the pump-out.

[unquote]

 

Dear Art,

 

As Paul mentioned we are faced, as always, with your valuable points this time regarding nitrogen blanketing. Indeed, we should appreciate for your kind support...

 

I only want your allowance to point out to a matter regarding the above mentioned point of yours about the portion of thermal inbreathing respect to total inbreathing (pump-out+thermal  inbreathing). Actually, your statement is completely right in small and moderate tanks, but in very large tanks applications the matter is going to be vice versa and the thermal portion of inbreathing can be significantly larger than that of liquid movement due to pump-out...Then sizing the valve only based on pump-out condition may lead to an undersized valve not to be able to handle the thermal inbreathing conditions...

[Art Montemayor]

Fallah:

 

Thank you for following up with a logical concern about the proper and correct way to size the required inert gas requirement flow rate to a storage tank while it is subjected to pump-out as well as in-breathing.  I concur with your comments and am in agreement with your statement that the inert gas flow rate required may be more related to the inbreathing instead of pump-out in the case of very large tanks.

 

You will note that I stated that in the past – in certain applications – I have found the opposite effect to be true.  In my specific cases, I recall that I was dealing with tanks in the capacities of 3,000 barrels and less.  This topic now brings to the forefront the definition of what constitutes a “large” storage tank.  I would consider a tank of 100,000 barrels as a large storage tank (134 ft diam. x 40 ft high); however, some experts have indicated that they consider this as a “small” tank.  So I am always inclined to define the tank size.

 

I recall when discussing this topic with my design group that it was decided that the scenario was that it was the coldest day in 50 years and that the pump-out rate was approximately 150 – 200 gpm, with a wind speed of 25 mph.  Under these given conditions there would be no agitation or turbulence in the tank’s vapor space and therefore, the convection currents in the vapor space were practically nil while the incoming inert gas was much hotter (25 ^oC) than the outside ambient temperature.  Therefore, it was concluded that the heat transfer rate between the tank’s wall and the inert gas blanket was expected to be very weak, with a negligible vapor volume decrease (and corresponding pressure decrease) due to temperature reduction.  This left the pump-out rate as being the main cause for a pressure decrease in the vapor space – during the pump-out time which was (as I recall) approximately 1.5 hours.  Considering that the time involved was relatively short, it was decided that the temperature effect on the tank’s vapor volume would be negligible during that period.

 

However, if the tank involved is a much larger one – over 100,000 barrels – and the wind speeds are increased at a very cold temperature, then I think it is conceivable that the effect of inbreathing may be predominant in this type of application – especially if the pump-out time is prolonged.  In any event each application should be calculated, checked, and carefully discussed in cases where a hazardous situation can arise.

 

Your thoughts and comments would be appreciated in view of the importance of this topic with regards to safety.

 

[Pete74]

Hi Rahulchem 2005,

I just came across your post.

If you look at the latest API 2000 (7th edition March 2004) Annex F there is guidance for Inert blanketing which from my interpretation allows your Inert blanketing rate to be lower than your Tankage PVRV rate as long as you satisfy the requirements based on the level of protection you select. (Obviously your PVRV still needs to be sized for the full rate to protect against vacuum).

 

Do any of the more experienced members of this forum have any experience of using Annex F of API2000?

 

First prize is obviously to size you blanketing system per the PVRV sizing basis (section 3.3.2.3.3) but in some cases ('large multiple tanks') this would result in an excessive nitrogen requirement for thermal inbreathing.

I don't know your specifics but each case must be looked individually and you must satisfy yourself that the design is safe.

 

 

Thanks

Pete