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Venting Calculation


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#1 vino

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Posted 31 August 2010 - 11:12 AM

Dear Forum members,

In my plant, we are using pressure vessels to store oxidiser. Nitrogen is used as blanketing medium over the oxidiser at a pressure of 2.5 bar. During overpressurization of vessels, due to evaporation of oxidizer or by level increase of oxidizer the nitrogen stream is vented to through a intentional vent line.

my question is

1. How to calculate the composition of oxidiser vapor in nitrogen stream and its effect on pressure rise.

2. How to estimate the venting quantity and its composition.

I have seen few threads discussed by ankur to use API standard 2000 (related excel sheet) to calculate the venting rate, whether same API standards are applicable to calculate the venting calculation of Pressure vessels designed by ASME code.

Edited by vino, 31 August 2010 - 11:19 AM.


#2 ankur2061

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Posted 31 August 2010 - 12:11 PM

Vino,

You have not specified the reasons or causes of probable overpressurization.

Venting out from any tank or vessel is due to following reasons:

1. Liquid movement in to the tank or vessel

2. Thermal Outbreathing due to increase in temperature of the contents of the tank or vessel (thermal expansion of vapor)

Venting or pressure increase due to chemical reaction is not covered in normal venting calculations and needs to be dealt separately.

So normal venting out is the same for atmospheric tanks or pressure vessels.

Regards,
Ankur.

Edited by ankur2061, 31 August 2010 - 12:13 PM.


#3 djack77494

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Posted 31 August 2010 - 02:03 PM

So normal venting out is the same for atmospheric tanks or pressure vessels.

API2000 applies ONLY to "atmospheric" storage tanks; it does not apply to pressure vessels which are covered in ASME Section VIII. That said, it may be possible to glean information about the rate at which gases must be vented by studying API2000 or other codes, even though they are not specifically meant for your application. Doing so is 100% at your risk, since you would not be using the codes as intended. My answers to your questions are as follows:

You and you alone must determine the composition of vent gases. It sounds like they could be the product of some reaction, and no code will have definitive procedures for those calculations. If this is true, then you and you alone must also determine how quickly gases are evolved from your system. (If it's simply a problem of displacing vapors at the top of the vessel, then Ankur has provided you with the path forward.) The effect of generated gases on the vessel's internal pressure is obtained from thermodynamic/physical chemistry principles. As a simplification for a first estimate, you can use the ideal gas law. You know the initial volume, gas MW, temperature, and pressure. Now determine what can cause the pressure to build to the PSV set pressure. You must have good knowledge of the system to do this, and we certainly are not in a good position to assist. Now calculate the situation right before a relief event. Get the vapor space temperature and gas MW. You should know the volume and the pressure is just the PSV setpoint, plus whatever overpressure you allow (say 10%). As additional gas is generated or evolved, it must be relieved. Your understanding of the system should allow for the relatively easy calculation of both the required relief rate and the properties (including composition) of the gas to be relieved. If you still do not see a soluition, you will need to supply much more detail regarding the problem to get meaningful help.

Edited by djack77494, 31 August 2010 - 02:05 PM.


#4 fallah

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Posted 01 September 2010 - 07:17 AM

API2000 applies ONLY to "atmospheric" storage tanks;


Just a little bit correction:

API 2000 applies to "atmospheric and low pressure (up to 15 psig) storage tanks".

#5 vino

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Posted 01 September 2010 - 12:13 PM

Dear members,

The reason for over pressurization is during filling of liquid oxidizer into the storage tank. (reply for the question of ankur).

Horizontal tank: 60 Cu.m

Blanketing medium: Nitrogen gas at pressure of 1.5 bar (g).

Oxidizer boiling point: 21 deg C at 1 bar.

Flash point: Data is not available.

Liquid filling rate: 3 cubic metre/hr

question:

1.I have seen in API 2000, for liquids whose boiling point less than 149 deg c, the outbreathing vent rate is given as 12 SCFH for 2.02 Nm3/hr filling rate and the thermal venting capacity is given as 10 Nm3/hr for 60 cu.m tank. Whether addition of this two quantity is sufficient to determine the normal venting rate.

2.Whether normal venting can be carried out by using a Pneumatic control valve. So that whenever tank pressure exceeds from 1.5 bar (g) to 2 bar(g) (with a margin of 0.5 bar pressure rise in tank), venting will be done to bring the pressure back to 1.5 bar.
Whether this 0.5 bar margin will be satisfied by the above calculated normal venting rate.

3.API std 2000 gives calculation of emergency venting rate for only atmospheric and low pressure storage tanks. I understand that this emergency venting rate is not applicable to pressure vessels. I hope everyone agrees this point.

4.I understand that normal venting for pressure vessels can be calculated by using API standard.

5.Whether safety relief valve should be sized for normal venting rate or emergency venting rate? Or Burst disk sizing should be based on emergency venting rate?

6.Is there any general equation to calculate the evaporation rate of liquid under different conditions of temperature and pressure.

with regards
vino

#6 ankur2061

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Posted 02 September 2010 - 04:15 AM

Vino,

1. Check the version of API 2000 you are using. The latest 6th edition of Nov. 2009 has changed the methodology of calculating normal venting (inbreathing and outbreathing) with significant increase in the inbreathing rates compared to the older 5th edition of 1998.

2. Yes. I was recently involved in a project where the vent line from the tank (low pressure) was routed to atmosphere with a control valve. The arrangement was a split control of the tank pressure from the inlet blanketing gas control valve and the outlet vent valve. By split control It is meant that when the tank pressure exceeds the set-point the outlet vent control valve opens and the inlet control valve closes and when the tank pressure goes below the set-point the inlet blanketing CV opens with closure of the outlet vent CV.

3. Emergency in context with API 2000 refers to the tank being exposed to an external fire. The emergency venting calculations considering external fire for low pressure tanks are covered in API 2000 and for pressure vessels the subject is dealt in API STD 521. The basic principles thougt are the same.

4. As explained earlier the fundamentals of liquid movement and thermal venting do not change just because it is a pressure vessel. The basics remain the same.

5. The safety relief valve or burst disk or emergency hatch in your case should be evaluated for fire-case relief based on the probability of fire and the volatility / explosion of the tank contents. Burst disk is only recommended if there possibilities of plugging the safety relief valve.

You could have the following over-pressure relief systems on your vessel as a maximum protection against failure due to any overpressure:

a. Normal vent with split control from inlet and outlet control valve
b. Safety Relief Valve or Burst disk sized for fire case (if fire case is found to be applicable)

6. Very basic evaporation rate guidelines are also given in API 2000. Additionally you can have a look API MPMS Chapter 19.4, Recommended Practice for Speciation of Evaporative Losses.

Hope this helps.

Regards,
Ankur




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