10 replies to this topic

[peeyar]

We have some vessels (Not Tanks) storing a chemical which has vapour pressure higher than atmosphere (30 psig). These vessels have been specified with Nitrogen padding (as they are toxic and very flammable). I was wondering if Nitrogen padding can help in preventing air ingress to avoid a flammable mixture.

In case of filling in the vapour of chemical will fill the space above liquid level and in case of emptying the pressure will drop and liquid will vapourize to fill the vapour space.
I was wondering if Nitrogen blanketing can be of any use. This is a new plant in design stage. The vent valve is connected to a high vent.
regds
PEEYAR

[proinwv]

First please be more specific in what you mean by " Not Tanks".

The purpose of blanketing here is to replace most of the air with an inert gas. This is accomplished by an initial purge followed by pressure control through a pressure sensitive gas delivery system. These have been well described in detail on this forum (and information is also available at www.ostand.com).

From your description, N2 blanketing is an appropriate method to control the content of the vapor space. O2 instrumentation is an additional method to monitor the results.

[peeyar]

Thanks for your response by Tanks I meant API650 type atoms tanks for which padding nitrogen is covered by code API2000
My question is ingress of O2 in a container which is above atmos press and liquid is not subcooled atmos temp is also not low
regds
PEEYAR

[proinwv]

You require venting to control the atmosphere in the tank. Both pressure and vacuum control.

[peeyar]

Paul
my question was as the vessel will always be above atmos the vapour space will be 100 pct chemical vapour which would be above UEL unless i am missing something
REGDS
PEEYAR

[proinwv]

I invite some our our Chem members to comment more on this as I am a M.E. and may miss something.

But, think about these things:

1) You start with a tank that has air in it.

2) The tank will breathe from transfer as well as diurnal effects

3) Breathing will require pressure and vacuum control whether it is from a blanketing system, or the atmosphere.

[djack77494]

I think the vessel should be thought of as a drum and not a tank. As I read this post, I'm thinking that the normal operating pressure of the vessel is 30psig, well above anything I'd refer to as a tank. It's certainly not an API650 tank, and I don't even think it falls within the realm of other "higher pressure" API tank standards.

With this in mind, I agree with Paul that nitrogen blanketing is an appropriate means of maintaining an inert atmosphere within the vessel. Air ingress seems most unlikely unless there's a lot more to the picture than has been revealed. I am concerned, however, that the OP is refering to API650 tanks and API2000 venting standards. Neither apply to this situation.

[S.AHMAD]

Without a diagram or P&ID I can only use my own imagination.

1. The storage vessel is operating at atmospheric pressure.
2. Due to high vapor pressure, the chemical is continuously venting.
3. Under this situation, ingress of air is very minimal or not possible due to this continuous venting even without N2 blanketing.
4. The purpose of N2 is to dilute the venting chemical such that the high vent will sufficiently disperse the chemical vapor-N2 mixture
5. Without N2, ground level concentration of the chemical vapor may exceed the allowable limit.
6. N2 helps dispersing chemical vapor.
7. Rate of chemical vaporization is proportional to the difference between vapor pressure an vessel pressure.
8. To eliminate vaporization, vessel pressure should be higher than vapor pressure.
9. Vessel pressure can be controlled using N2 (split range pressure control system)

Hope the above comments help.

[Asifkazi]

If you are not satisfied with N2 blanketing, in addition to this you may go for Protego inline pressure and vaccum relief valve connected to wet scrruber through inline flame arrester as the chemical is flammable and toxic.

In this case you need to specify the vaccum and presusre ratings for valve and flame arrester operation or let protego experts evaluate it or you may go for online calculator available to their web

http://www.protego.d...home/index.html

Attached find the file for the equipment with tanks API2000.

Hope this will make you clear.

Regards
Asif Gul Kazi

Attached Files

•  Kapitel_7_allgemeine_Beschreibung_GB.pdf   150.53KB   132 downloads

[fallah]

We have some vessels (Not Tanks) storing a chemical which has vapour pressure higher than atmosphere (30 psig). These vessels have been specified with Nitrogen padding (as they are toxic and very flammable). I was wondering if Nitrogen padding can help in preventing air ingress to avoid a flammable mixture.

In case of filling in the vapour of chemical will fill the space above liquid level and in case of emptying the pressure will drop and liquid will vapourize to fill the vapour space.
I was wondering if Nitrogen blanketing can be of any use. This is a new plant in design stage. The vent valve is connected to a high vent.
regds
PEEYAR

Peeyar,

You failed to submit any information about the fluid, operating temperature, emptying rate, vessel design pressure/vacuum,....

Anyway, considering the operating conditions while there is no vent for inbreathing (no nitrogen padding) are you sure emptying rate would be such that following liquid vaporizing can prevent the vessel to be damaged due to vacuum occurance?

Nitrogen padding of high vapor pressure fluids is not a strange matter. It is performed, as an example in methanol storage vessels.

Fallah

[brennl]

yeah! i think most of the people know about the Nitrogen padding of high vapor pressure fluids is not a strange matter. and we also know that It is performed, as an example in methanol storage vessels.