You have two questions. I will rephrase them to what I understand you to ask and then reply.
Question One "Why are there different refrigerants?" Check the operating pressures of the two DeC2 columns. The condensing temperature is different for the different pressures so you are using different levels of refrigeration.
Question Two "Why are the columns not the same diameter from top to bottom?" The expected internal traffic is used in designing the column diameters. The columns would likely operate fine if they had the wide diameter at both the top and bottom. But since the traffic was expected to be significantly lower in one section, the diameter of the shell in that section was reduced to save capital cost.
If you have access to a steady-state process simulator, these columns are pretty easy to model. Building and reviewing a model may give you a better feel for what is happening inside the columns.