Hello,
I am working on a chemical system design for a brackish water desalination plant that requires large volumes of HCl for pH adjustment (~80,000 gal in poly atmospheric tanks) and the client is specifying an indoor facility. To minimize corrosion potential inside of the facility, we are considering a blanket system to flush acid vapors to a designated exhaust/scrubbing system. The firm that I am at does not have many other engineers that have worked on systems larger than small water treatment plant storage designs to evaluate this concept, so I thought it would be beneficial to inquire here for general advice as well.
This is the general idea:
- Roof intake piping brings fresh air down to vent inlet header on storage tanks
- Air sweeps through head space of storage tanks (although not sure of reasonable velocities yet)
- Slightly acidic air exits through exhaust vent and joins header connecting other tank exhausts (sized large for pneumatic tank filling, estimated air flow with API2000 7th App.D.7)
- Exhaust header goes to inlet for either small venturi or absorber column to scrub acid emissions
- Roof mounted dispersion exhaust blower; suction from blower drives air flow throughout the system (haven't done any real calc's yet)
Does a system like this seem reasonable? From an emission standpoint, I'm not sure how to best estimate the HCl transferred to the sweeping air from convection. Is it worth going through more traditional mass transfer estimates? Is it reasonable to assume--from a mass loading standpoint--that a worst case scenario approximation would be vapor-liquid-equilibrium? This second option is my initial inclination, even though it seems like overkill for the estimate.
Overall priority on this design is to minimize fugitive emissions escaping into the facility, from both a corrosion and operator safety standpoint, and provide an integrated scrubbing system. I've searched around quite a bit for a similar design concept and have found a lot on acid scrubbers and blanket gas systems, but have not seen very much similar to this overall design idea. General feedback or suggestions would be greatly appreciated.
Thank you,
Tony