Hi
I really need some help. I have projects that consist in separate isopropyl alcohol (IPA), isopropyl ether and water by a distillation process. The only specification design is to recover 99.5 wt% of IPA from a mixture of IPA 58 wt%, Isopropyl ether 6wt% and water 36 wt%.
I don't have any conditions of operation specified. I know that the mixture will have an azeotrope. How can I determine the operation conditions? Also how can I set which kind of separation will be better (azeotropic or extraction)?
Can you recommend me some literature?
Thanks a lot
Jenny
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Isopropanol Ether And Water Distillation
Started by Guest_Jen_*, Apr 09 2004 05:45 PM
1 reply to this topic
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#1 Guest_Jen_*
Posted 09 April 2004 - 05:45 PM
#2
Posted 20 April 2004 - 10:39 AM
Hi
I have not checked the azeotropes, but would assume that in a distillation an heteroazeotrope water-DIPE would go on on top and that the alcool would stay in the bottoms. A IPA-water azeotrope is also highly likely to exist.
A residue curve , starting with your feed mixture would be of help
First identify all azeotropes and their boiling points
I would then check wheter you have a chance of handling your mixture as if it wer a binary system, made of
either (DIPE water azeotrope/ isopropanol)
of (DIPE water azeotrope/ isopropanol water azeoptrope)
and attempt graphical methods (Mc Cabe & thiele)
in any case it would give you a starting point to feed a computer program that handlesq LLE systems. You will need a computer model if you use a computer. in such case I'd advise NRTL or UNIQUAC as a second choice.
You mention extractive distillation. note that pervaporartion can be used also for such separations
Also you need to specify BOTH the purity required (ie 99.5%wt) and the fraction of initial feed you want to recover.
Hope this will help. If you need more, please supply recovery and purity specifications as well as azeotropic information.
I have not checked the azeotropes, but would assume that in a distillation an heteroazeotrope water-DIPE would go on on top and that the alcool would stay in the bottoms. A IPA-water azeotrope is also highly likely to exist.
A residue curve , starting with your feed mixture would be of help
First identify all azeotropes and their boiling points
I would then check wheter you have a chance of handling your mixture as if it wer a binary system, made of
either (DIPE water azeotrope/ isopropanol)
of (DIPE water azeotrope/ isopropanol water azeoptrope)
and attempt graphical methods (Mc Cabe & thiele)
in any case it would give you a starting point to feed a computer program that handlesq LLE systems. You will need a computer model if you use a computer. in such case I'd advise NRTL or UNIQUAC as a second choice.
You mention extractive distillation. note that pervaporartion can be used also for such separations
Also you need to specify BOTH the purity required (ie 99.5%wt) and the fraction of initial feed you want to recover.
Hope this will help. If you need more, please supply recovery and purity specifications as well as azeotropic information.
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