9 replies to this topic

[chemtan]

I have a case to share here:

MEA is being pumped from storage tank at rate of 3 cu.m per minute (2 pumps, one operating)
Tank capacity is 837 cu.m (4 hours of intermittent storage)

I do have to install a PSV on this tank but the question is below:
A nitrogen blanketing system is required so that vaccum does not get build up when pumping out of the tank. I was just considering that for some reason, the control valve on nitrogen line fails.

1. should I allow for a 2 way breathing PSV here? (MEA reacts with O2 which is not desired)
2. Should I:
a - install an outbreathing PSV
b - install Pressure Control Loop that would sense the vaccum and switch off pumps
c - Keep tank min design pressure to sustain vaccum

I would want to go for option '2' here but dont know how much vaccum shall I consider in 2-c ?

Any help \ suggestions are welcome.

A sketch of the system is attached, although not very detailed, I tried to give an idea of process flow.

Regards

Attached Files

•  Amine_Tank_Sketch.pdf   24.67KB   89 downloads

[proinwv]

If you would search this forum you would find several previous topics dealing with these types of questions.

First, the vacuum vent would be for backup should the nitrogen supply not be adequate to prevent a tank collapse due to vacuum. Yes, you could ingest atmospheric air under this condition; the alternative being a possible tank collapse and spill and injury.

As to the value for the vacuum setting, please consult the tank manufacturer for the MAWV rating and size accordingly.

[Art Montemayor]

Chemtan:

I consider an 837 m3 tank for this type of application as a large tank. Therefore, you should normally have full fabrication documentation on this tank – data such as the MAWP and MAWV as well as the related calculations. If, for some unfortunate circumstances, you do not have this information then you should proceed to acquire it as soon as you can because you will need it as a basis for setting the relief pressure and vacuum specifications on your PVSV. This information, unfortunately, is usually absent from the files of many storage tanks because so-called “atmospheric” vessels are treated as being relatively un-important or “benign”. However, the opposite often proves to be the case when one considers the hazard scenario of having this tank rupture due to over-pressure or vacuum and spill its 837 m3 of amine solution unto operations personnel.

The case of having air enter an amine storage tank due to a vacuum valve opening is a common one that must be addressed. Usually, the incident is not immediately damaging to the solution if the air is purged out as soon as possible afterwards. Therefore, what is done is that a vacuum detection switch is installed to alarm when the vacuum breaker activates. This can be a limit switch or a pressure switch. As long as operators are made aware of the event, a subsequent procedure to purge out the air can be undertaken at a convenient time. The logic of this operation is based on the importance of knowing if a vacuum is triggered and then finding out the cause first to cure the problem. I would rather apply this method than rely on having a storage tank able to withstand a vacuum condition. I don’t believe that a reasonable vacuum design can be justified for a storage tank - which is always the underlying concern in trying to keep storage tanks from collapsing under vacuum.

Summarizing, I recommend:

1) Installing a PVSV – a combined, adequate pressure and vacuum relief valve;
2) Installing a vacuum detection system that monitors and records any vacuum event;
3) Applying the previously described procedure to re-establish the inert blanket.

A vacuum imposed on an API type of storage tank is a serious and hazardous event. It is far more practical and expedient to allow the vacuum breaker to do its work - as Paul has inferred - than to try to avoid the air coming into the tank. Any "damage" done to the MEA solution will be minimal when compared to what could happen to personnel and equipment should the tank collapse.

[chemtan]

Got it...

Thanks for the help.

Tanveer

[proinwv]

Tanver, I shall add one comment to Art's reply.

Once you know the MAWP then you can do a careful evaluation of the acceptable setpoints for the pressure relief valves, taking into consideration the pressure rise upon opening as well as the reseat pressures.

Once this is done, it will be obvious where the blanket setpoint is to be. Keeping this as high as safely possible reduces the possibility of falling into the vacuum range. Often tanks operate at very low blanket setpoints because of the inability of the tank to tolerate the pressure. It is often done to save costs of blanket gas.

When operating at low sets, say 1/2"wc, it is not uncommon for the operation to drop into vacuum due to the pressure droop of a PRV, or the responsed of a control valve. As to saving gas, it is very little as it is a ratio to the absolute pressure.

[Mazfar]

Sir,

What is the advise in case the tank contains a flammable liquid like ethylene dichloride.

Regards

[proinwv]

Mazfar,

I am not sure what your question is, but as far as blanketing and venting are concerned the rules are the same for any fluid. The actual values of the venting volumes will vary based upon the physical properties according to API 2000.

Please restate your question with more detail.

[Mazfar]

Tank is provided with a Nitrogen blanket , breather PSV and emergency (Fire) releif for flammable liquid storage.

In case Nitrogen blanket stops or malfunctions , breather will suck in air.

Air sucking in can cause flammable mixture inside the tank.The breather protects the tanks from vacuum , but brings in air increasing risk of flammable atmosphere inside tank.

One thought was simply alarm in dcs , in case the tank goes in low pressure , additionally shutdown pump automatically.

What is the practice in this type of scenario.

[fallah]

Tank is provided with a Nitrogen blanket , breather PSV and emergency (Fire) releif for flammable liquid storage.

In case Nitrogen blanket stops or malfunctions , breather will suck in air.

Air sucking in can cause flammable mixture inside the tank.The breather protects the tanks from vacuum , but brings in air increasing risk of flammable atmosphere inside tank.

One thought was simply alarm in dcs , in case the tank goes in low pressure , additionally shutdown pump automatically.

What is the practice in this type of scenario.

I was thinking that an example would illustrate the matter.

An actual control and safety system for a MDEA storage tank i was faced, specified as below:

-A N2 blanketing PCV with the set point equal to 0.015 barg
-A pressure relieving PCV with the set point equal to 0.02 barg
-A PSV for vacuum and pressure relief as last safeguard with the set points equal to +0.025 and - 0.0025 barg
-A LT for setting High and Low Alarms on Level
-A LT for setting High High and Low Low Alarms on Level along with an Interlock on Low Low for pump shut down

-It should be considered that design pressure of the tank is -5 mbarg/Full of Liquid+25 mbarg

Hope this help out

[proinwv]

In addition to the instrumentation, a second blanketing system, cascaded, can offer protection too.